Abstract
Functional passivation agents have been shown to effectively optimize the crystallization process and passivate defects on the surface and grain boundaries. People have conducted extensive research on the passivation mechanisms of various passivation agents to obtain more effective passivation agents. Researchers are gradually focusing on natural ingredients in the search for suitable passivation agents due to the wide variety, green color, and ease of production. As a result, the natural chlorophyll component chlorin e6 (CE‐6) is first combined with perovskite solar cells (PSCs) to improve their performance. Following the incorporation of CE‐6 into the perovskite layer, various functional groups of CE‐6 are used to effectively reduce traps on the perovskite surface, suppress charge recombination at the interface, improve carrier transfer rate and carrier extraction efficiency, and ultimately improve efficiency. The optimal device achieves a power conversion efficiency (PCE) of 21.14% and maintains its initial PCE of 84% after being stored in a room‐temperature air environment for 500 h. Furthermore, semitransparent PSC (ST‐PSC) is made with 13.33% PCE and 5.53% average visible light transmittance. The findings show that natural material CE‐6 performs well in the perovskite layer and confirms the promising prospects for optimizing ST‐PSC.
Herein, the natural chlorophyll component chlorin e6 is combined with perovskite solar cells for the first time. Compared with the pristine device, the power conversion efficiency increases from 18.81% to 21.14%. By combining optimized perovskite films with ultrathin Ag electrodes, chlorin e6 still maintains the same optimization effect in semitransparent devices with 13.33% power conversion efficiency.