Charge transport comparison of FA, MA and Cs lead halide perovskite single crystals for radiation detection

Stephanie H. Bennett; Joydip Ghosh; Eric Gros-Daillon; Ferdinand Lédée; Javier Mayén Guillén; Jean-Marie Verilhac; Julien Zaccaro; Duck Young Chung; Vladislav Klepov; Mercouri G. Kanatzidis; Paul J. Sellin

doi:10.3389/fdest.2023.1249892

Journal article

Charge transport comparison of FA, MA and Cs lead halide perovskite single crystals for radiation detection

Stephanie H. Bennett, Joydip Ghosh, Eric Gros-Daillon, Ferdinand Lédée, Javier Mayén Guillén, Jean-Marie Verilhac, Julien Zaccaro, Duck Young Chung, Vladislav Klepov, Mercouri G. Kanatzidis, …

Frontiers in Detector Science and Technology, Vol.1, 1249892

14/09/2023

DOI: https://doi.org/10.3389/fdest.2023.1249892

Abstract

We report a systematic comparison of the charge transport and radiation detection properties of inorganic and organic metal bromide single crystal perovskites. We studied the performance of Bridgman-grown CsPbBr 3 single crystals, together with solution-grown FAPbBr 3 and MAPbBr 3 single crystals. Laser time of flight is used to measure the drift mobilities for all samples, and we report a maxium mobility value of 121 ± 10 cm V −1 s −1 for CsPbBr 3 . Alpha particle measurements were used to assess the mobility-lifetime products, with values recorded in the range of 2 × 10 −4 cm 2 V −1 to 1 × 10 −3 cm 2 V −1 . Low temperature measurements showed an increase in bulk resistivity at temperatures down to 260 K, but no significant change to the drift mobilities. The overall performance of the Cs, FA and MA samples is compared and their potential for use in gamma spectroscopy measurements is discussed.

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Title: Charge transport comparison of FA, MA and Cs lead halide perovskite single crystals for radiation detection
Creators: Stephanie H. Bennett - University of Surrey
Joydip Ghosh - University of Surrey
Eric Gros-Daillon - Université Grenoble Alpes
Ferdinand Lédée - Université Grenoble Alpes
Javier Mayén Guillén
Jean-Marie Verilhac
Julien Zaccaro - Institut Néel
Duck Young Chung - Argonne National Laboratory
Vladislav Klepov - Northwestern University
Mercouri G. Kanatzidis - Argonne National Laboratory
Paul J. Sellin - University of Surrey
Publication Details: Frontiers in Detector Science and Technology, Vol.1, 1249892
Publisher: Frontiers Media
Date published: 14/09/2023
Date accepted: 24/08/2023
Grants: PEROXIS, 871336, European Union (Belgium, Brussels) - EU
Grant note: This work was funded by the US Defense Threat Reduction Agency under Basic Research contract HDTRA1-18-1-0019, and also through the DTRA Interaction of Ionizing Radiation with Matter University Research Alliance (IIRM-URA) under contract number HDTRA1-20-2-0002. The project or effort depicted was or is sponsored by the Department of the Defense, Defense Threat Reduction Agency. The content of the information does not necessarily reflect the position or the policy of the federal government, and no official endorsement should be inferred. This work has also has received funding from the European Union’s Horizon 2020 research and innovation program under the Photonics Public Private Partnership (www.photonics21.org) with the project PEROXIS under Grant Agreement No. 871336. The work at Argonne National Laboratory was supported by the Department of Energy, National Nuclear Security Administration, Office of Defense Nuclear Nonproliferation Research and Development under Contract No. DEAC02-06CH11357 and the Department of Energy, Basic Energy Sciences (for exploration of Hi-Z detector materials for synchrotron detector applications).
Identifiers: 99818284902346
Copyright: © 2023 Bennett, Ghosh, Gros-Daillon, Lédée, Mayén Guillén, Verilhac, Zaccaro, Chung, Klepov, Kanatzidis and Sellin. This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
Academic Unit: School of Maths and Physics
Language: English
Resource Type: Journal article

Charge transport comparison of FA, MA and Cs lead halide perovskite single crystals for radiation detection

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