Light-fluorous TEMPO: reagent, spin trap and stable free radical

Adrian P. Dobbs; Peter Jones; Mark J. Penny; Stephen E. Rigby

doi:10.1016/j.tet.2009.04.078

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Light-fluorous TEMPO: reagent, spin trap and stable free radical

Journal article

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Light-fluorous TEMPO: reagent, spin trap and stable free radical

Adrian P. Dobbs, Peter Jones, Mark J. Penny and Stephen E. Rigby

Tetrahedron, Vol.65(27), pp.5271-5277

04/07/2009

DOI: https://doi.org/10.1016/j.tet.2009.04.078

Abstract

ESR spectra

Fluorous solid-phase extraction

Fluorous-TEMPO

Oxidation reaction

Radical spin trap

The synthesis of two light-fluorous TEMPO derivatives is reported, along with their fluorous-organic solvent partition coefficients and their ESR spectra. Applications of the fluorous-TEMPO reagents in oxidation reactions and as radical traps are discussed. [Display omitted]

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Title: Light-fluorous TEMPO: reagent, spin trap and stable free radical
Creators: Adrian P. Dobbs - Queen Mary University of London
Peter Jones - Pfizer
Mark J. Penny - Queen Mary University of London
Stephen E. Rigby - Queen Mary University of London
Publication Details: Tetrahedron, Vol.65(27), pp.5271-5277
Publisher: Elsevier Ltd
Number of pages: 7
Publication Date: 04/07/2009
Identifiers: 99961156802346; WOS:000267587600018
Academic Unit: School of Chemistry and Chemical Engineering; Department of Chemistry
Language: English
Resource Type: Journal article

Light-fluorous TEMPO: reagent, spin trap and stable free radical

Abstract

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