Abstract
During the manufacture of a composite cathode for lithium-sulfur (Li-S) batteries it is important to realize homogeneous infiltration of a specified amount of sulfur, targeted to be at least 5 mg cm(-2) to achieve good battery performance in terms of high energy density. A model of the sulfur infiltration is presented in this study, taking into account the pore size distribution of the porous cathode host, phase transitions in sulfur, and formation of different sulfur allotropes, depending on pore size, formation energy and available thermal energy. Simulations of sulfur infiltration into an activated carbon fabric at a hot-plate temperature of 175 degrees C for two hours predicted a composite cathode with 41 wt% sulfur (8.3 mg cm(-2)), in excellent agreement with the experiment. The pore size distribution of the porous carbon host proved critical for both the extent and form of retained sulfur, where pores below 0.4 nm could not accommodate any sulfur, pores between 0.4 and 0.7 nm retained S-4 and S-6 allotropes, and pores between 0.7 and 1.5 nm contained S-8.