Abstract
In recent years, microbial electrochemical systems (MESs) have demonstrated to be an environmentally friendly technology for wastewater treatment and simultaneous production of value-added products or energy. However, practical applications of MESs for the treatment of recalcitrant wastewater are limited by their low power output and slow rates of pollutant biodegradation. As a novel technology, hybrid MESs integrating biodegradation and photocatalysis have shown great potential to accelerate the degradation of bio-recalcitrant pollutants and increase the system output. In this review, we summarize recent advances of photo-assisted MESs for enhanced removal of recalcitrant pollutants, and present further discussion about the synergistic effect of biodegradation and photocatalysis. In addition, we analyse in detail different set-up configurations, discuss mechanisms of photo-enhanced extracellular electron transfer, and briefly present ongoing research cases. Finally, we highlight the current limitations and corresponding research gaps, and propose insights for future research.