Abstract
Two-dimensional (2D) organic–inorganic hybrid halide perovskites have recently attracted extensive attention for electronic and optoelectronic applications due to their tunable properties and superior stability compared with their three-dimensional (3D) counterparts. Here, we report two kinds of organic cation (linear butylamine (BA) and branched isobutylamine (i-BA)) tailored CsPbBr3 crystals, namely (BA)2CsPb2Br7 and (i-BA)2CsPb2Br7, grown by the temperature-cooling method. The organic cations' adjustable anisotropic structure, optoelectronic properties and X-ray detection performance have been systematically investigated. By shortening the spacer cation from BA to i-BA, the degree of anisotropy in 2D perovskite crystals is decreased, which may be ascribed to the reduced interlayer distance and barrier height resulting from the enhanced electronic coupling between neighboring organic cations. In particular, the device based on the (BA)2CsPb2Br7 crystal along the ab plane exhibits superior X-ray sensitivity up to 13.26 mC Gy−1 cm−2 at a relatively low electric field of 2.53 V mm−1, owing to the multiple quantum well structure that restricts the charge carrier transport within the ab plane resulting in efficient charge collection. Simultaneously, a superior long-term working stability is obtained under a high X-ray dose rate of 278.4 μGy s−1. We anticipate that these findings will be helpful for the development of Ruddlesden–Popper perovskites for future research and applications.