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Mechano-responsive polymer solutions based on CO2 supersaturation: shaking-induced phase transitions and self-assembly or dissociation of polymeric nanoparticles
Journal article   Peer reviewed

Mechano-responsive polymer solutions based on CO2 supersaturation: shaking-induced phase transitions and self-assembly or dissociation of polymeric nanoparticles

PJ Roth, JY Quek, Y Zhu, BM Blunden and AB Lowe
CHEMICAL COMMUNICATIONS, Vol.50(67), pp.9561-9564
28/08/2014

Abstract

Science & Technology Physical Sciences Chemistry Multidisciplinary Chemistry CHEMISTRY MULTIDISCIPLINARY CRITICAL-SOLUTION TEMPERATURE HYDROGELS MICELLES WATER PH Chemistry
Mechanical stimulation of supersaturated aqueous CO2 solutions is accompanied by a pH increase within seconds. In solutions of tailored homo- and AB diblock copolymers this is exploited to induce micelle formation, or, taking advantage of an aqueous upper critical solution temperature transition, nanoparticle disassembly
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