Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

Y Pei; J-M Noy; Peter Roth; A Lowe

doi:10.1039/c4py01558d

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Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

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Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

Y Pei, J-M Noy, Peter Roth and A Lowe

POLYMER CHEMISTRY, Vol.6(11), pp.1928-1931

01/01/2015

DOI: https://doi.org/10.1039/c4py01558d

Abstract

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Physical Sciences

Polymer Science

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Chemistry

RAFT dispersion polymerization (RAFTDP) is used to prepare reactive nanoparticles via the incorporation of Passerini-derived methacrylic comonomers containing pentafluorophenyl (PFP) groups. Copolymerization of 2-(dimethylamino)ethyl methacrylate with a Passerini comonomer gives copolymers suitable as macro-CTAs for ethanolic RAFTDP of 3-phenylpropyl methacrylate. Reaction of the PFP residues with functional thiols offers an approach for preparing surface modified nanoparticles.

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Title: Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification
Creators: Y Pei
J-M Noy
Peter Roth
A Lowe
Publication Details: POLYMER CHEMISTRY, Vol.6(11), pp.1928-1931
Publisher: ROYAL SOC CHEMISTRY
Date published: 01/01/2015
Date submitted: 19/04/2016
Identifiers: 99516763702346
Academic Unit: Department of Chemistry
Language: English
Resource Type: Journal article

Thiol-reactive Passerini-methacrylates and polymorphic surface functional soft matter nanoparticles via ethanolic RAFT dispersion polymerization and post-synthesis modification

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