Isomers in near-spherical Z = 51, antimony isotopes are reported here for the first time using fusion-fission reactions between Al-27 and a pulsed Hf-178 beam of energy, 1150 MeV. gamma rays were observed from the decay of isomeric states with half-lives, T-1/2 = 200(30) and 52(3) mu s, and angular momenta I = (25/2) and I-pi = 23(+)/2, in Sb-121,Sb-123, respectively. These states are proposed to correspond to nu(h(11/2))(2) configurations, coupled to an odd d(5/2) or g(7/2) proton. Nanosecond isomers were also identified at I-pi = 19(-)/2 [T-1/2 = 8.5(5) ns] in Sb-121 and I-pi = (15(-)/2) [T-1/2 = 37(4) ns] in Sb-123. Information on spins and parities of states in these nuclei was obtained using a combination of angular correlation and intensity-balance measurements. The configurations of states in these nuclei are discussed using a combination of spin/energy systematics and shell-model calculations for neighboring tin isotones and antimony isotopes.