Abstract
Our group has recently focused on obtaining new molecular magnets based on radical BEDT-TTF or TTF derivatives. In these series, the aim is to combine the magnetic and conducting properties in the same material via the radical donor. We report here the structural and the physical properties of three salts with donors TTF (ferrimagnetic insulator), TMTTF (antiferromagnetic insulator) and TMTSF (paramagnetic semiconductor), containing the Reinekes anion derivative [Cr(NCS)4(phenanthroline)]. The role of the crystal packing in determining the physical properties is discussed.