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Does the gamma Polymorph of Glycine Nucleate Faster? A Quantitative Study of Nucleation from Aqueous Solution
Journal article   Open access  Peer reviewed

Does the gamma Polymorph of Glycine Nucleate Faster? A Quantitative Study of Nucleation from Aqueous Solution

Laurie Little, Richard Sear and Joseph Keddie
Crystal Growth and Design, Vol.15(11), pp.5345-5354
01/11/2015

Abstract

Science & Technology Physical Sciences Technology Chemistry Multidisciplinary Crystallography Materials Science Multidisciplinary Chemistry Materials Science CRYSTAL NUCLEATION CRYSTALLIZATION GROWTH EMULSIONS KINETICS ALPHA MECHANISMS DROPLETS INSIGHTS RATES
We advance the quantitative study of nucleation by combining the study of hundreds of samples, with statistical tests for reproducibility, and for well-defined nucleation rates. Unlike in most previous work, we find that in the samples that nucleate after the first hour of our experiment the equilibrium glycine polymorph predominates over the alpha form.
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