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One-dimensional anionic metal-organic chain generated from(Tetraphenylphosphonium)benzoquinonediiminedisulfonate and CuI
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One-dimensional anionic metal-organic chain generated from(Tetraphenylphosphonium)benzoquinonediiminedisulfonate and CuI

H Akutsu, J-I Yamada, S Nakatsuji and SS Turner
X-ray Structure Analysis Online, Vol.29(10), pp.41-42
06/2013

Abstract

The title compound, (CHP)(CHNOS)CuI.0.34HO, was obtained by the slow evaporation of a solvent from an acetonitrile solution containing a mixture of (PPh)N,N'-disulfobenzoquinonediimine and CuI. The structure consists of a one-dimensional metal-organic framework of the dianion and CuI. The anionic chains are surrounded by relatively large counter-cations, and are thus well isolated from each other.
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http://dx.doi.org/10.2116/xraystruct.29.41View
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