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The reaction between Nafion sulfonyl fluoride precursor membrane and 1,4-dimethylpiperazine does not yield reliable anion-exchange membranes
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The reaction between Nafion sulfonyl fluoride precursor membrane and 1,4-dimethylpiperazine does not yield reliable anion-exchange membranes

DM Hillman, SH Stephens, SD Poynton, S Murphy, AL Ong and John Varcoe
JOURNAL OF MATERIALS CHEMISTRY A, Vol.1(4), pp.1018-1021
01/01/2013

Abstract

Science & Technology Physical Sciences Technology Chemistry Physical Energy & Fuels Materials Science Multidisciplinary Chemistry Materials Science ELECTROLYTE FUEL-CELLS ALKALINE POLYMER STABILITY RESISTANT
Recent reports that the reaction between Nafion sulfonyl fluoride precursor and the cyclic diamine 1,4-dimethylpiperazine yields stable anion-exchange membranes appear to be premature. On aqueous work up, membranes with high cation-exchange capacities and zero anion-exchange capacities are produced.
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