Silenes as novel synthetic reagents: identification of a practical method for silene generation and trapping.

MB Berry; RJ Griffiths; MJ Sanganee; PG Steel; DK Whelligan

doi:10.1039/B404166F

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Journal article

Silenes as novel synthetic reagents: identification of a practical method for silene generation and trapping.

MB Berry, RJ Griffiths, MJ Sanganee, PG Steel and DK Whelligan

Org Biomol Chem, Vol.2(16), pp.2381-2392

21/08/2004

DOI: https://doi.org/10.1039/B404166F

Abstract

Indicators and Reagents

Lithium

Magnetic Resonance Spectroscopy

Models

Chemical

Molecular Structure

Silene

Solubility

Temperature

The elucidation of a robust and reliable sequence for the generation of highly reactive transient silenes from simple aldehydes is described. The key step involves a silyl-modified Peterson olefination which critically depends on the presence of a sub-stoichiometric amount of soluble lithium salts (LiBr).

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Title: Silenes as novel synthetic reagents: identification of a practical method for silene generation and trapping.
Creators: MB Berry
RJ Griffiths
MJ Sanganee
PG Steel
DK Whelligan
Publication Details: Org Biomol Chem, Vol.2(16), pp.2381-2392
Date published: 21/08/2004
Date submitted: 17/05/2017
Identifiers: 99511588702346
Academic Unit: University of Surrey
Language: English
Resource Type: Journal article

Silenes as novel synthetic reagents: identification of a practical method for silene generation and trapping.

Abstract

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