Abstract
Among various types of alternative energy devices, solid oxide fuel cells (SOFCs) operating at low temperatures (300‐600°C) show the advantages for both stationary and mobile electricity production. Proton‐conducting oxides as electrolyte materials play a critical role in the low‐temperature SOFCs (LT‐SOFCs). This review summarizes progress in proton‐conducting solid oxide electrolytes for LT‐SOFCs from materials to devices, with emphases on (1) strategies that have been proposed to tune the structures and properties of proton‐conducting oxides and ceramics, (2) techniques that have been employed for improving the performance of the protonic ceramic‐based SOFCs (known as PCFCs), and (3) challenges and opportunities in the development of proton‐conducting electrolyte‐based PCFCs.
Protonic ceramic fuel cells have attracted the increased attention in the last 20 years. This review summarizes progress in proton‐conducting solid‐oxide electrolytes for low temperature protonic ceramic fuel cells.