Abstract
Hybrid or composite heterostructured electrode materials have been widely studied for their potential application in electrochemical energy storage. Whereas their physical or chemical properties could be affected significantly by modulating the heterogeneous interface, the underlying mechanisms are not yet fully understood. In this work, we fabricated an electrochemical energy storage device with a MoS
2
nanosheet/MnO
2
nanowire heterostructure and designed two charge/discharge channels to study the effect of the heterogeneous interface on the energy storage performances. Electrochemical measurements show that a capacity improvement of over 50% is achieved when the metal current collector was in contact with the MnO
2
instead of the MoS
2
side. We propose that this enhancement is due to the unidirectional conductivity of the MoS
2
/MnO
2
heterogeneous interface, resulting from the unimpeded electrical transport in the MnO
2
-MoS
2
channel along with the blocking effect on the electron transport in the MoS
2
-MnO
2
channel, which leads to reaction kinetics optimization. The present study thus provides important insights that will improve our understanding of heterostructured electrode materials for electrochemical energy storage.