Abstract
Here we present dielectric relaxation experiments carried out in semicrystalline poly (trimethylene terephthalate) (PTT) samples covering a broad range of crystallinity values. Special attention has been devoted to characterize the two extremes of low and high crystallinity. In particular a high temperature relaxation in the dielectric spectra of highly crystalline PTT, attributed to a Maxwell-Wagner-Sillars process, has been revealed. Moreover, the existence of ordering phenomena during the induction period prior to crystallization has been characterized by dielectric spectroscopy. © 2013 Elsevier Ltd. All rights reserved.