Abstract
The potential of using carbonized slash pine bark as a substitute for activated carbon was examined in this study. The bark was carbonized by slow heating in nitrogen for 6·5 h to 672°C. The BET‐N2 surface area, average micropore and mesopore diameter, and micropore volume were 332 m2 g−1 21·7 Å, and 0·125 cm3 g−1, respectively. The adsorption capacities for phenol and pentachlorophenol (PCP) at pH 2 and pH 8 were evaluated. The Langmuir equation provided a slightly better fit than the Freundlich equation to two sets of phenol data. The calculated Freundlich constants, K = 0·41–0·58 mmol/g/(mmol dm−3)1/n and 1/n = 0·30–0·41, were lower and higher, respectively, than literature values for activated carbons. The adsorption capacity of the carbonized bark was much lower for PCP than for phenol. The protonated and anionic PCP isotherms were Type II or III, respectively, in the Brunauer classification. The BET equation provided the best fit to protonated PCP isotherm data. The anionic PCP data were fitted to both the BET model and an equation used in the literature to represent phosphate adsorption on activated carbons. Non‐linear regression of the data for both phenol and PCP adsorption with the Freundlich, Langmuir and BET equations generally gave more accurate param‐eters, compared with the use of linearized equations to obtain the parameters. © 1998 SCI.