A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]

N Kanbayashi; H Akutsu; J-I Yamada; S Nakatsuji; SS Turner

doi:10.1016/j.inoche.2012.04.028

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A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]

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A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]

N Kanbayashi, H Akutsu, J-I Yamada, S Nakatsuji and SS Turner

Inorganic Chemistry Communications, Vol.21, pp.122-124

07/2012

DOI: https://doi.org/10.1016/j.inoche.2012.04.028

Abstract

A novel ferrocene-containing dianion, Fe(C H - CH(CH )NHCOCH SO ) (1), has been prepared. The oxidation potential of the PPh salt is + 0.35 V (vs. SCE in PhCN), indicating that it is a stronger donor than TTF (tetrathiafulvalene) by + 0.03 V. The dianion provided a TTF salt, the structure and physical properties of which are reported. © 2012 Elsevier B.V. All rights reserved.

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Title: A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]
Creators: N Kanbayashi
H Akutsu
J-I Yamada
S Nakatsuji
SS Turner
Publication Details: Inorganic Chemistry Communications, Vol.21, pp.122-124
Date published: 07/2012
Date submitted: 17/09/2013
Identifiers: 99516592102346
Academic Unit: University of Surrey
Resource Type: Journal article

A new ferrocene-containing charge-transfer salt, (TTF) [Fe(C H -CH(CH )NHCOCH SO ) ]

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