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A Fuel Reforming and Ignition Coupling Strategy with Nanosecond Surface Dielectric Barrier Discharge for Ammonia Combustion Enhancement
Doctoral Thesis   Open access

A Fuel Reforming and Ignition Coupling Strategy with Nanosecond Surface Dielectric Barrier Discharge for Ammonia Combustion Enhancement

Deyan Kong
University of Surrey
Doctor of Philosophy (PhD), University of Surrey
29/05/2026
DOI:
https://doi.org/10.15126/thesis.902065

Abstract

Ammonia Nanosecond Surface Dielectric Barrier Discharge Fuel Reforming Plasma Assisted Ignition

Ammonia (NH3) is a promising carbon-free fuel for future energy systems due to its high energy density and ease of storage and transportation. However, its practical applications are currently limited by significant challenges such as high ignition energy and low burning velocity, resulting in difficult ignition and unstable combustion. Improving the ignition and combustion behaviours of NH3/air mixtures is essential to enable reliable, high-efficiency operation. This study proposes and examines a two-stage, single-device nanosecond surface dielectric barrier discharge (nSDBD) strategy coupling plasma-assisted NH3 reforming (PAAR) with plasma-assisted NH3 combustion (PAAC). Experiments were conducted in a constant volume chamber (CVC) and complemented by a zero-dimensional model for mechanistic interpretation. The discharge parameters of direct nSDBD ignition was first optimised, followed by a quantification of the effects of ignition discharge parameters, operating conditions (equivalence ratio, initial pressure, initial temperature), and discharge configurations. Finally, a joint optimisation of reforming parameters and ignition parameters for the proposed two-stage single-device strategy was performed. PAAR seeds a reactive reservoir including H2 at approximately 0.1% of the mixture. Compared with direct ignition, the two-stage PAAR–coupled PAAC strategy achieves higher supplied energy, faster ignition, and more intense combustion. Simulations agree with experiments and elucidate the key radical pools and reaction pathways responsible for reforming-enabled ignition facilitation and combustion enhancement. This research delivers practical parameter windows and device guidelines, supporting compact nSDBD implementation for robust NH3 ignition and utilisation.

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