The raw data is the experimental data of the paper 'Facet-Dependent Metal-Support Interactions in Cobalt-Ceria Binary Oxides: Linking Ceria Morphology (rods vs. cubes) to Redox Behaviour and CO Oxidation ' which is accepted in the Catalysis Science and Technology' of Royal Society of Chemistry. The file format is in txt and is open access format. All the listed files include the catalytic data and material characterisation including SEM, TEM,XRD and XPS.